An article Chemoselective Transfer Hydrogenation of alpha,beta-Unsaturated Ketones Catalyzed by Iridium Complexes WOS:000615971600001 published article about ASYMMETRIC TRANSFER HYDROGENATION in [Xia, Yanping; Ouyang, Lu; Liao, Jianhua; Yang, Xiao; Luo, Renshi] Gannan Med Univ, Sch Pharm, Ganzhou 341000, Jiangxi, Peoples R China in 2021.0, Cited 72.0. Name: Chalcone. The Name is Chalcone. Through research, I have a further understanding and discovery of 94-41-7
Efficient chemoselective transfer hydrogenation of the C=C bond of alpha,beta-unsaturated ketones has been developed, using the iridium complexes containing pyridine-imidazolidinyl ligands as catalysts and formic acid as a hydrogen source. In comparison with organic solvents or H2O as solvent, the mixed solvents of H2O and MeOH are critical for a high catalytic chemoselective transformation. This chemoselective transfer hydrogenation can be carried out in air, which is operationally simple, allowing a wide variety of alpha,beta-unsaturated substrates with different functional groups (electron-donating and electron-withdrawing substituents) leading to chemoselective transfer hydrogenation in excellent yields. The practical application of this protocol is demonstrated by a gram-scale transformation.
Name: Chalcone. About Chalcone, If you have any questions, you can contact Xia, YP; Ouyang, L; Liao, JH; Yang, X; Luo, RS or concate me.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com