I found the field of Chemistry very interesting. Saw the article Total Syntheses of (-)-Deoxoapodine, (-)-Kopsifoline D, and (-)-Beninine published in 2020.0. Formula: C8H18O3, Reprint Addresses Peng, XS (corresponding author), Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong 100051, Peoples R China.; Peng, XS (corresponding author), Chinese Univ Hong Kong, State Key Lab Synthet Chem, Shatin, Hong Kong 100051, Peoples R China.; Peng, XS (corresponding author), Chinese Univ Hong Kong Shenzhen, Sch Sci & Engn, Shenzhen 518172, Peoples R China.; Peng, XS (corresponding author), Chinese Univ Hong Kong, Shenzhen Municipal Key Lab Chem Synth Med Organ M, Shenzhen Res Inst, Shenzhen 518507, Peoples R China.. The CAS is 78-39-7. Through research, I have a further understanding and discovery of 1,1,1-Triethoxyethane
The total syntheses of Aspidosperma and Kopsia alkaloids (-)-deoxoapodine, (-)-kopsifoline D, and (-)-beninine are described through a domino deprotection-Michael addition-nucleophilic substitution protocol to assemble the core framework in efficient steps. Corey-Bakshi-Shibata reduction was employed to afford the enantioenriched intermediate for the total syntheses of the aforementioned alkaloids. The chirality was shown to completely transfer to the backbone using Johnson-Claisen rearrangement. The enantioselective total syntheses of (-)-kopsifoline D and (-)-beninine were accomplished for the first time. Our strategy opens up practical avenues for the total synthesis of structurally similar alkaloids.
About 1,1,1-Triethoxyethane, If you have any questions, you can contact Zhou, YG; Wong, HNC; Peng, XS or concate me.. Formula: C8H18O3
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com