Synthetic Route of 76186-04-4, Career opportunities within science and technology are seeing unprecedented growth across the world, and those who study chemistry or another natural science at university now have increasingly better career prospects. In a article, 76186-04-4, molcular formula is C6H11NS2, introducing its new discovery.
The direct and stereocontrolled addition of (S)-4-isopropyl-N-(2-pivaloyloxyacetyl)-1,3-thiazolidine-2-thione to dialkyl acetals of aromatic and alpha,beta-unsaturated aldehydes catalyzed by 2.5?5 mol-% of a nickel(II) complex permits the synthesis of diastereomerically pure and fully protected anti aldol adducts in good to high yields. The catalytic species is formed in situ from commercially available and easy to handle (Me3P)2NiCl2, which makes this reaction a direct, catalytic, and experimentally simple approach to the asymmetric anti glycolate aldol reaction.
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Reference：
Quinuclidine – Wikipedia,
Quinuclidine | C7H753N | ChemSpider