Some examples of the diverse research done by chemistry experts include discovery of new medicines and vaccines,category: thiazolidine, improving understanding of environmental issues, and development of new chemical products and materials. In a document type is Article, and a compound is mentioned, 76186-04-4, (S)-4-Isopropylthiazolidine-2-thione, introducing its new discovery.
Lagunamide C is a depsipeptide natural product with low nM cytotoxicity towards numerous cancer cell lines. Synthetically, it is disconnected to a pentapeptide backbone and polyketide unit that possesses four stereogenic centers, of which two of centers are in question (C38 & 40). Our model system highlights a high-selective aldol addition via a Crimmin’s auxiliary setting the C40 ester linkage, and a non-facially selective cyclopropanation with subsequent ring opening for the installation of the C38 methyl center.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. category: thiazolidine, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 76186-04-4, in my other articles.
Reference：
Quinuclidine – Wikipedia,
Quinuclidine | C7H727N | ChemSpider