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Titanium enolates from chiral N-propanoyl-1,3-thiazolidine-2-thiones containing bulky substituents at C4 turned out to be excellent platforms to get highly stereocontrolled cross-coupling reactions with acetals. Related oxazolidinethiones also afforded good results, but the corresponding oxazolidinones resulted completely unselective for such reactions, which proves that an exocyclic C{double bond, long}S bond is essential to attain a synthetically useful stereocontrol.
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Reference：
Quinuclidine – Wikipedia,
Quinuclidine | C7H718N | ChemSpider