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Synthesis and antibacterial activity of a series of 2-trifluoromethylbenzimidazole-thiazolidinone derivatives
A series of 2-phenyl-3-(2-(trifluoromethyl)-1H-benzoimidazol-6-yl)thiazolidin-4-one derivatives were synthesized from p-nitro-o-phenylenediamine in a three-step reaction. Their structures were elucidated by NMR and mass spectral data. The synthesized compounds showed excellent antibacterial activity ranging from 3-fold, to greater than 100-fold higher than the standard antibiotics, ciprofloxacin and levofloxacin. Compounds 3d (2 ‘-Br), 3j (4 ‘-Br), and 3l (4 ‘-NO2) displayed a broad spectrum of activity against the strains tested (0.14-38.33 mu M). The brominated derivatives 3d and 3j showed excellent activity against the Gram-positive bacterial strains (MBC between 0.12 and 35.46 mu M), while the nitro derivative 3l showed excellent activity against all four Gram-negative strains tested (MBC between 0.15 and 9.58 mu M).
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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com