Extracurricular laboratory: Discover of Tris(2-chloroethyl) phosphate

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Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 115-96-8, Name is Tris(2-chloroethyl) phosphate, molecular formula is C6H12Cl3O4P. In an article, author is Tuncel, Senel Teke,once mentioned of 115-96-8, Application In Synthesis of Tris(2-chloroethyl) phosphate.

Synthesis of thiazol-2-imines from the reduction of single enantiomer 2-imino-thiazolidin-4-ones followed by a spontaneous water elimination

Chiral hemiaminals (5-8RR and 5-8SS) have been synthesized from the corresponding 2-iminothiazolidine-4-ones (1-4RR and 1-4SS) by LiAlH4 reductions stereoselectively and were then converted to single enantiomer thiazol-2-imines (9-12RR and 9-12SS) by a water elimination reaction. The kinetics of the dehydration reactions which occurred spontaneously both in the solid state and in the solution have been followed by time dependent H-1 nuclear magnetic resonance spectroscopy. The corresponding first order rate constants and free energies of activation values for the conversions have been reported.

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Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com