Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Yennawar, Hemant P., once mentioned the application of 593-85-1, Name is guanidinecarbonate, molecular formula is C3H12N6O3, molecular weight is 180.1658, MDL number is MFCD00013029, category is thiazolidines. Now introduce a scientific discovery about this category, Category: thiazolidines.
Crystal structure of a 1:1 adduct of triphenyltin chloride with 3-cyclohexhyl-2-phenyl-1,3-thiazoildin-4-one
In the centrosymmetric (racemic) title compound, chlorido(3-cyclohexhyl-2-pheny1-1,3-thiazolidin-4-one-kappa O)triphenyltin(IV), [Sn(C6H5)(3)Cl(C15H19NOS)], the tin(IV) atom exhibits a trigonal-bipyramidal coordination geometry with the three phenyl groups in equatorial positions and the chloride anion and ligand oxygen atom present at axial sites [O -Sn- Cl = 175.07 (14)degrees]. The thiazolidinone ring of the ligand adopts an envelope conformation with the S atom as the flap. The dihedral angles between the heterocycle ring plane (all atoms) are 44.3 (9)degrees with respect to the pendant C-phenyl plane and 34.3 (11)degrees to the N-cyclohexyl ring (all atoms). The C-phenyl and N-cyclohexyl ring are close to orthogonal to each other, with a dihedral angle of 81.1 (4)degrees between them. In the crystal, molecules are linked by weak C-H center dot center dot center dot Cl hydrogen bonds to generate [001] chains.
If you are interested in 593-85-1, you can contact me at any time and look forward to more communication. Category: thiazolidines.
Reference:
Thiazolidine – Wikipedia,
,Thiazolidine – ScienceDirect.com